As far as the fifth disc is concerned, I counted 18 specially arranged tracks during my in-game recording of the 3DS version, including two different variations of the Prelude (one with just the acapella and another with the backing melody), and two different versions of the Prologue/Final Fantasy theme. I'd heard there are one or two new arrangements featured on the iOS version -- I haven't listened to those, but maybe they'll find their way on the CD release as well?
The arrangements are largely relegated to the various menu screens, the title, and the ending. Here's what disc 5's tracklisting could potentially look like:
* FF1 - Chaos Shrine (Chaos Shrine Menu BGM)
* FF1 - Cornelia Castle (Series Play Menu BGM)
* FF3 - Return of the Warrior (Series Play Results BGM)
* FF4 - Kingdom of Baron (Museum BGM)
* FF4 - Parom & Palom (Tutorial BGM)
* FF6 - Setzer (Party Edit BGM)
* FF7 - Highwind Takes to the Skies (Main Menu BGM)
* FF7 - Racing Chocobos ~ Place Your Bets! (Street Pass/ProfiCard BGM)
* FF9 - Hunter's Chance (Song Select BGM)
* FF9 - Rose of May (Museum Collection VGM)
* FFX - Thunder Plains (ProfiCard Edit BGM)
* FFXII - The Royal City of Rabanastre ~ City Ward Upper Level (DLC Menu BGM)
* FFXIII - Blinded By Light (Challenge Mode BGM)
* Prelude (Opening Logos)
* Prelude (Title Theme)
* Fanfare (Song Cleared BGM)
* Final Fantasy (Museum Collection Autoplay BGM)
* Final Fantasy (Staff Roll)
You can find a handful of in-game recordings on Youtube to gauge arrangement quality. I've uploaded two of my personal faves myself, Highwind Takes to the Skies and the Final Fantasy Staff Roll.